Camex HD reactive dye is a range of novel reactive dyestuffs. These are developed for meeting increasing demand of Economy, Efficiency & Ecology. Camex HD reactive dyestuffs are highly purified form of multiple reactive systems. These dyes have more active sites to attack the primary and secondary hydroxyl group of cellulose. These dyes show excellent coverage of dead cotton and have good migration property.
Camex HD dyes have high build up and are mainly recommended for medium to dark shades. It is recommended for exhaust dyeing and continuous dyeing for cellulosics blends.
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The main features of Camex HD reactive dyestuffs are |
- Excellent reproducibility and hence batch to batch variation is minimized.
- Superb colour yield and high rate of fixation
- High fixation leaves less colour residue in effluent.
- Easy wash off process saves water.
- Warm dyeing with efficiency and consumes less energy
- Better fastness properties.
- Wide range of application since it is suitable for all types of cellulosics materials like yarn, fiber, piece dyeing and garments.
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| Camex HD reactive dyes are preferred over conventional Dyes due to |
- Exhaust dyeing at 60°c
- Very high solubility in the dyebath, even in very short liquor ratio.
- Parallel fixation curves of all three dyes in trichromy.
- Good degree of Fixation
- Resistance to alkaline hydrolysis (Before, during and after dyeing)
- Similar affinity & speed of fixation
- Similar speed of diffusion / leveling.
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| Dyeing Methods |
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These dyes are suitable for dyeing with different methods and also have wide choice of equipments to be used for dyeing. The dyeing method depends upon the type of substrate to be used and also the machinery to be used. Ttiese dyes are suitable for winch dyeing, package dyeing, jigger dyeing and beam dyeing. |
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| (1) Exhaust Dyeing: |
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Minutes |
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| Raise temperature At 40°c |
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Load machine, run liquor and / or fabric. Ensure that pH is below 7. Adjust with acetic acid if necessary |
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05 |
Add predissolved Dye |
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10 |
continue dyeing |
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02 |
add 20 g/l Salt |
| Raise temperature |
10 |
continue dyeing |
| To 60°c @ 1 °c/min while |
05 |
add remaining salt |
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10 |
continue dyeing |
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30 |
Continue dyeing at 60°c to allow a uniform tempreture to be achived throughout the machine. |
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15 |
add Soda Ash slowly |
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60-90 |
Dye at 60°c |
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Check Shade |
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| Migration Method |
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| (2) Winch Dyeing |
Winches are mainly used for dyeing knitted and delicate woven fabrics. In this method dyestuff solution is added over a period of 15 minutes and goods are run at 40° C. salt addition in then followed at same temperature and goods are run for 10-15 minutes. After running the goods properly in dyes and salt, alkali is added within 10-15 minutes and required temperature is attained and goods are run for 60-90 minutes. Depending depth of shade.
It is very important to add chemicals and dyestuff slowly as there are chances to get unevenness during dyeing since the fabric is in rope form. Finally fabric is washed soaped, washed and dried. |
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| Winch Dyeing Machine |
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| (3) Jigger Dyeing |
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| Load the goods on jigger |
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1 end |
| Set dyebath at room temp, with required water + 0.5-1 g/l Camasequest N |
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1 end |
| Add half the dye solution & run the fabric |
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1 end |
| Add remaining half dye solution & run the fabric |
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1 end |
| Start raising the temp. & add 10% amount of the total salt in 2 ends |
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2 ends |
| Add 30% of total salt in 2 ends |
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2 ends |
| Add remaining salt in 2 ends |
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2 ends |
| At 60° C run the fabric |
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2 ends |
| Add soda at 60° C 1/2 the amount |
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1 end |
| Add remaining half amount of soda & run the fabric |
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1 end |
| At 60° C run the fabric |
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4 end |
| Cold ash |
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2 ends |
| Hot wash |
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2 ends |
| Soaping at boil |
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2 ends |
| Hot wash |
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2 ends |
| Cold water |
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2 ends |
| Total |
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28 ends |
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| Jigger Dyeing Machine |
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| Requirment of Electrolyte And Alkali For Camex HD Dyeing |
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Depth of Shade
(% on weight of goods) |
Common salt OR Glauber salt (GPL) |
Alkali (GPL) |
Fixation Time |
| Unmercerised cotton |
Mercerize cotton/ viscose |
Soda ash |
(Mix Alkali)
Soda ash +
Caustic soda (38° Be) |
< 0.5% |
20 |
10 |
10 |
5 + 0.5 |
45 |
| 0.5 - 1.0% |
30 |
20 |
15 |
5 + 0.5 |
45 |
| 1.0 - 2.0% |
40 |
30 |
20 |
5 + 1.0 |
60 |
| 2.0 - 3.0% |
50 |
40 |
20 |
5 + 1.0 |
60 |
| 3.0 - 4.0% |
60 |
50 |
20 |
5 + 1.0 |
60 |
| 4.0 -5.0% |
70 |
60 |
20 |
5 + 1.0 |
60 |
| 5.0 -6.0% |
80 |
70 |
20 |
5 + 2.0 |
60 |
| >6.0% |
80 |
70 |
20 |
5 + 2.0 |
90 |
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| * Do not use mix Alkali, while dyeing of viscose fabric and their blends. |
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| Camex HD Padding Methods |
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| (1) Padding (Pad Batch Long Term) |
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This is a simple application method where Caustic and Silicate are used. The goods are batched and then washed, soaped, washed and dried.
Padding liquor is prepared as follows |
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| Recipe |
Camexil Reactive dyes |
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X g/l |
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Urea |
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50-100 |
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Sodium Silicate |
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as per table |
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Caustic Solution |
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as per table |
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Wetting agent if required |
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1-3 g/l |
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Method : The dye powder is first properly dissolved with warm water and required amount of urea is added. Sodium silicate and Caustic solution is prepared separately in required quantity of water and mixed with dye solution just before padding. The fabric is then padded with 70% Expression. It is either batched on a beam or kept on wooden planks and covered with plastic sheets. Care must be that air does not enter and dwell time of 18 -24 hrs. is given and then washed, soaped, washed and dried. If required deep shades may be given dye fixing treatment. |
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| Alkali requirements : |
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| For padding and batching temperature at 30 - 35°C |
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Silicate
Be °Tw |
Weight Ratio
Na20: Sio2 |
Qty of Silicate GPL |
Qty of caustic Solution
Required of 32.5% - cc/lit. |
Dyestuff
upto 30 GPL |
Dyestuff
above 30 GPL |
| 37-40 / 69-77 |
1:3.3 |
135 |
13 |
18 |
| 40-42 / 77-82 |
1:3.3 |
120 |
11 |
16 |
| 48-50 / 100-106 |
1:2.6 |
100 |
05 |
10 |
| 58-60 / 134-142 |
1:2.1 |
85 |
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04 |
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Cold - Pad - Batch Machine |
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| Camex HD Dyes Printing Methods |
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| Different Printing Methods can be used for printing. |
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| (1) Print - Dry - Steam - Wash - Dry. |
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| Recipe |
Camective HD Dyes |
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X Part |
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Urea |
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40-100 Parts |
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Water |
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200 Parts |
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Sodium Alginate Paste (6-8%) |
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500 Parts |
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Resist Salt |
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10 Parts |
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Soda-bicarbonate |
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10-25 Parts |
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Water |
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Balance |
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Total |
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1000 Parts |
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Process : The fabric is first printed with the above paste and dried. It is then steamed with saturated steam for 10-15 minutes at 100 - 105°C in Star ager or for 5 - 7 minutes in a continuous steamer and then washed and dried. |
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| (2) Print - Dry - Pad - Batch - Wash - Dry |
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| Recipe |
Camex HD dyes |
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10-60 Parts |
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Water |
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200 Parts |
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Sodium Alginate Paste (6-8%) |
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600 Parts |
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Resist Salt |
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10 Parts |
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Urea |
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0-20 Parts |
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Water or Thickner |
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Balance |
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Total |
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1000 Parts |
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Process : Print the fabric with above paste and dry. It is then padded through 100-110° Tw sodium silicate solution containing 4-6 cc/l caustic soda of 32.5%. It is batched and covered with plastic sheet. Dwell time is about 16-24 hrs. Depending on dyestuff used. Finally it is washed and dried. This is the most simple and economical method which is widely used because of its reproducibility and brilliancy of prints. |
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| (3) Print - Dry - Chemical Pad - Wash - Dry |
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| Recipe |
Camezol HD dyes |
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X Parts |
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Water |
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320 Parts |
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Sodium Alginate Paste (6-8%) |
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500 Parts |
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Resist Salt |
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10 Parts |
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Sodium Hexa Meta Phosphate |
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10 Parts |
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Water or Thickner |
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Balance |
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Total |
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1000 Parts |
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Process : The Fabric is printed with the above paste and dried. It is then passed through hot fixation bath maintained at 95 - 100° C containing following chemicals. |
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Glauber Salt |
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20 gms/Ltr. |
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Soda Ash |
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150 gms/Ltr. |
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Potash |
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50 gms / Ltr. |
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Solid Caustic Soda |
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25 - 30 gms/Ltr. |
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The fixation of prints takes 5-12 seconds. After fixation the prints are washed immediately and dried. |
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| (4) Print - Dry - Bake - Wash - Dry. |
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| Recipe |
Camex HD dyes |
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X Parts |
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Urea |
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100-200 Parts |
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Water |
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150 - 200 Parts |
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Sodium Alginate Paste (6-8%) |
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400 Parts |
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Sodium Bi-Carbonate |
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15 - 25 parts |
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Resist Salt |
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10 Parts |
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Water |
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Balance |
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Total |
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1000 Parts |
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The fabric is printed with the above paste and dried. It is then baked for 5 minutes at 140°C for 4 minutes at 150°C in dry heat. Finally the fabric is washed and dried. This method has to be followed with lot of accuracy for reproducing the results. Slight change in any parameters is likely to change the required results. |
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| General Washing Method |
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| In order to achieve maximum fastness properties a proper wash off is essential for the dyed and printed goods. |
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| Minutes |
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| 15 |
Rinse Cold |
| 15-20 |
Rinse Warm |
| 10 |
Neutralization |
| 15-30 |
Soap at the boil. For Very heavy depth shades soaping required twice. |
| 10 |
Rinse Warm Rinse Cold until clear solution is obtained. |
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For medium to heavy shades an after treatment with 1 - 2 g/l dye fixing agent is given at room temperature (40° C at acidic pH of 5 - 5.5 to improve fastness properties. |
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L.YELLOW HDRN |
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G.YELLOW HDR |
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YELLOW HD3R |
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RED HDRN |
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RED HD3B |
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BLUE HDGF |
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NAVY BLE HDR |
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BLACK HDR |
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